Formation of the N-oxides of heteroaromatic nitrogen compounds by perfluorinated oxaziridines

被引：7

作者：

Balsarini, C ^{[1
]}

Novo, B ^{[1
]}

Resnati, G ^{[1
]}

机构：

[1] CNR,DIPARTIMENTO CHIM,CTR STUDIO SOSTANZE ORGAN NAT,I-20131 MILAN,ITALY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 80卷 / 01期

关键词：

perfluorinated oxaziridines; N-oxide; N-imine; oxidation; heterocycle;

D O I：

10.1016/S0022-1139(96)03456-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

On treatment with perfluoro-cis-2,3-dialkyloxaziridines, mono-, bi-, and tricyclic nitrogen heteroaromatics afford the corresponding N-oxides under mild reaction conditions and in medium to high yields. The course of the reaction is not altered by the presence of various residues on the ring or in side chains and the N-oxides of polyfunctional, naturally occurring compounds have been prepared.

引用

页码：31 / 34

页数：4

共 30 条

[1] ALKALOID N-OXIDES
ALBINI, A
[J]. HETEROCYCLES, 1992, 34 (10) : 1973 - 2002
[2] ANDREAE S, 1991, SYNTHESIS-STUTTGART, P327
[3] THE CHEMISTRY OF 3-TRIFLUOROMETHYL-PERFLUORO-AZA-2-BUTENE AND THE SYNTHESIS OF A NEW OXAZIRIDINE - 3,3-BISTRIFLUOROMETHYL-2-TRIFLUOROMETHYLOXAZIRIDINE
BRAGANTE, L
DESMARTEAU, DD
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1991, 53 (02) : 181 - 197
[4] A STEREOSELECTIVE AND PREPARATIVE ENTRY TO 1,2-ANHYDROSUGARS THROUGH OXIDATION OF GLYCALS WITH PERFLUORO-CIS-2,3-DIALKYLOXAZIRIDINES
CAVICCHIOLI, M
MELE, A
MONTANARI, V
RESNATI, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) : 901 - 902
[5] OXYFUNCTIONALIZATION REACTIONS BY PERFLUORO CIS-2,3-DIALKYTOXAZIRIDINES - ENANTIOSELECTIVE CONVERSION OF SILANES INTO SILANOLS
CAVICCHIOLI, M
MONTANARI, V
RESNATI, G
[J]. TETRAHEDRON LETTERS, 1994, 35 (34) : 6329 - 6330
[6] CHAMBON P, 1969, CR ACAD SCI D NAT, P523
[7] APPLICATIONS OF OXAZIRIDINES IN ORGANIC-SYNTHESIS
DAVIS, FA
SHEPPARD, AC
[J]. TETRAHEDRON, 1989, 45 (18) : 5703 - 5742
[8] DELTSOVA DP, 1979, IAN SSSR KH, V8, P1788
[9] MILD AND SELECTIVE OXYGENATION OF SULFIDES TO SULFOXIDES AND SULFONES BY PERFLUORO-CIS-2,3-DIALKYLOXAZIRIDINES
DESMARTEAU, DD
PETROV, VA
MONTANARI, V
PREGNOLATO, M
RESNATI, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (10) : 2762 - 2765
[10] OXIDATION OF ALCOHOLS BY PERFLUORO-CIS-2,3-DIALKYL OXAZIRIDINES
DESMARTEAU, DD
PETROV, VA
MONTANARI, V
PREGNOLATO, M
RESNATI, G
[J]. TETRAHEDRON LETTERS, 1992, 33 (47) : 7245 - 7248

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