PGSE NMR studies on RAPTA derivatives:: Evidence for the formation of H-bonded dicationic species

被引：28

作者：

Bolano, Sandra ^{[2
]}

Ciancaleoni, Gianluca ^{[1
]}

Bravo, Jorge ^{[2
]}

Gonsalvi, Luca ^{[3
]}

Macchioni, Alceo ^{[1
]}

Peruzzini, Maurizio ^{[3
]}

机构：

[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Vigo, Fac Quim, Dept Quim Inorgan, Vigo 36310, Spain

[3] CNR ICCOM, I-50019 Sesto Fiorentino, FI, Italy

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 07期

关键词：

D O I：

10.1021/om701131s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-aggregation tendency of RAPTA complexes {[Ru(eta(6)-p-cymene){PTA(-R)}Cl-2]X, R = H (1BPh(4) and 1PF(6)) and Me (2BPh(4) and 2OTf), and [Ru(eta(6)-p-cymene)(PTA)(2)Cl]X (3BPh(4) and 3BF(4))} in acetone-d(6) was investigated by means of diffusion NMR spectroscopy. On increasing the concentration, the protonated species (1X) undergoes intercationic self-aggregation driven by hydrogen bonding that leads to the formation of 1(2)(2+) dications and a small amount of 1(2)X(+) ion triples.

引用

页码：1649 / 1652

页数：4

共 45 条

[1] Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA=1,3,5-triaza-7-phosphaadamantane) [J].

Akbayeva, DN ;

Gonsalvi, L ;

Oberhauser, W ;

Peruzzini, M ;

Vizza, F ;

Brüggeller, P ;

Romerosa, A ;

Sava, G ;

Bergamo, A .

CHEMICAL COMMUNICATIONS, 2003, (02) :264-265

[2] [Ru(η6-p-cymene)Cl2(pta)] (pta=1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane):: a water soluble compound that exhibits pH dependent DNA binding providing selectivity for diseased cells [J].

Allardyce, CS ;

Dyson, PJ ;

Ellis, DJ ;

Heath, SL .

CHEMICAL COMMUNICATIONS, 2001, (15) :1396-1397

[3] Intermolecular hydrogen•••metal interactions.: The crystal structure of {cis-[PdCl2(TPA)2]}2•H2O, a water-soluble palladium(II) tertiary phosphine complex [J].

Alyea, EC ;

Ferguson, G ;

Kannan, S .

CHEMICAL COMMUNICATIONS, 1998, (03) :345-346

[4] Strategy to tether organometallic ruthenium-arene anticancer compounds to recombinant human serum albumin [J].

Ang, Wee Han ;

Daldini, Elisa ;

Juillerat-Jeanneret, Lucienne ;

Dyson, Paul J. .

INORGANIC CHEMISTRY, 2007, 46 (22) :9048-9050

[5] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU-CENTER-DOT-CENTER-DOT-CENTER-DOT-AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] (VOL 34, PG 75, 1995) [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP ;

ASSMANN, B ;

ANGERMAIER, K ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1995, 34 (09) :2490-2490

[6] STRUCTURES AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) .2. MULTIPLE-STATE EMISSION FROM (TPA)AUX (X=CL, BR, I) COMPLEXES [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1995, 34 (20) :4965-4972

[7] NMR investigation of non-covalent aggregation of coordination compounds ranging from dimers and ion pairs up to nano-aggregates [J].

Bellachioma, Gianfranco ;

Ciancaleoni, Gianluca ;

Zuccaccia, Cristiano ;

Zuccaccia, Daniele ;

Macchioni, Alceo .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (21-22) :2224-2238

[8] (ETA-6-HEXAMETHYLBENZENE)RUTHENIUM COMPLEXES [J].

BENNETT, MA ;

HUANG, TN ;

MATHESON, TW ;

SMITH, AK .

INORGANIC SYNTHESES, 1982, 21 :74-78

[9] The effect of counterion/ligand interplay on the activity and stereoselectivity of palladium(II)-diimine catalysts for CO/p-methylstyrene copolymerization [J].

Binotti, Barbara ;

Bellachioma, Gianfranco ;

Cardaci, Giuseppe ;

Carfagna, Carla ;

Zuccaccia, Cristiano ;

Macchioni, Alceo .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (05) :1570-1582

[10] Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane) [J].

Bolaño, S ;

Gonsalvi, L ;

Zanobini, F ;

Vizza, F ;

Bertolasi, V ;

Romerosa, A ;

Peruzzini, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 224 (1-2) :61-70

← 1 2 3 4 5 →