Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments

被引：42

作者：

Cui, XB

Xu, JQ

Sun, YH

Li, Y

Ye, L

Yang, GY

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China

[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[4] Baicheng Normal Coll, Dept Chem, Biacheng 137000, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; polyoxometalate; arsenic-vanadium cluster; one-dimensional chain; crystal structure;

D O I：

10.1016/j.inoche.2003.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Cu(en)(2)](1.5)[H3As6V15O42(H2O)].3H(2)O I (en = ethylenediamine) has been synthesized and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction analysis. Crystal structure analysis reveals that compound I is not only the first example of one-dimensional sinusoidal chain structure constructed from polyoxometalates and coordination complex fragments but also the first example of one-dimensional chain of polyoxometalates where clusters are connected by one coordination complex fragment and two coordination complex fragments alternatively. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：58 / 61

页数：4

共 32 条

[1] THE AUTOMATIC SEARCHING FOR CHEMICAL-BONDS IN INORGANIC CRYSTAL-STRUCTURES [J].