Two- and three-dimensional frameworks constructed from bicapped Keggin clusters

被引：83

作者：

Duan, LM

Pan, CL

Xu, JQ ^{[1
]}

Cui, XB

Xie, FT

Wang, TG

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[3] Inner Mongolia Univ Nationalities, Coll Chem, Tongliao 028000, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 14期

关键词：

polyoxometalates; hydrothermal synthesis; cluster compounds; crystal structure;

D O I：

10.1002/ejic.200300070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel two- and three-dimensional solid materials [Cu(en)(2)(H2O)]{(PMo8VV6O42)-V-VI-V-IV[Cu-0.5(en)](3)}.5.5H(2)O and H-3{(VMo8V6O42)-Mo-V-V-VI-O-IV[Cu(en)(2)](4)}[MoO4](2).14H(2)O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are based on mixed Mo/V bicapped Keggin clusters interconnected through the transition metal complex moieties. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

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收藏

页码：2578 / 2581

页数：4

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