Oxygen migration at Pt/HfO2/Pt interface under bias operation

被引:59
作者
Nagata, T. [1 ]
Haemori, M. [1 ]
Yamashita, Y. [1 ,2 ]
Yoshikawa, H. [2 ]
Iwashita, Y. [1 ,3 ]
Kobayashi, K. [2 ]
Chikyow, T. [1 ]
机构
[1] Natl Inst Mat Sci, Adv Elect Mat Ctr, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, NIMS Beamline Stn SPring 8, Sayo, Hyogo 6795148, Japan
[3] Meiji Univ, Sch Sci & Technol, Tama Ku, Kanagawa 2148571, Japan
关键词
electrical conductivity; hafnium compounds; interface states; MIM devices; platinum; X-ray photoelectron spectra; X-RAY PHOTOEMISSION; FILMS; OXIDE; ENTHALPY; MEMORY;
D O I
10.1063/1.3483756
中图分类号
O59 [应用物理学];
学科分类号
摘要
The interfacial electronic states of a Pt/HfO2/Pt diode were investigated by using hard x-ray photoelectron spectroscopy under bias operation. The application of a forward bias to the Pt/HfO2/Pt diode increased the Pt-O bonding peak, providing evidence of Pt electrode oxidization and oxygen vacancy formation around the Pt/HfO2 interface. Under a reverse bias, hafnium was drawn to the Pt electrode, where it took part in Hf-Pt bonding. We achieved the direct observation of oxygen migration at a Pt/HfO2 interface under device operation, which is the key to controlling the electrical properties of metals on oxides.
引用
收藏
页数:3
相关论文
共 24 条
[11]  
Moulder J.F., 1979, HDB XRAY PHOTOELECTR
[12]   Standard enthalpy of formation of platinum hydrous oxide [J].
Nagano, Y .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 69 (03) :831-839
[13]   Influences of annealing in reducing and oxidizing ambients on flatband voltage properties of HfO2 gate stack structures [J].
Ohmori, K. ;
Ahmet, P. ;
Yoshitake, M. ;
Chikyow, T. ;
Shiraishi, K. ;
Yamabe, K. ;
Watanabe, H. ;
Akasaka, Y. ;
Nara, Y. ;
Chang, K.-S. ;
Green, M. L. ;
Yamada, K. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (08)
[15]   Electronic transport in Ta2O5 resistive switch [J].
Sakamoto, Toshitsugu ;
Lister, Kevin ;
Banno, Naoki ;
Hasegawa, Tsuyoshi ;
Terabe, Kazuya ;
Aono, Masakazu .
APPLIED PHYSICS LETTERS, 2007, 91 (09)
[16]   Local chemical state change in Co-O resistance random access memory [J].
Shima, Hisashi ;
Takano, Fumiyoshi ;
Muramatsu, Hidenobu ;
Yamazaki, Masashi ;
Akinaga, Hiroyuki ;
Kogure, Akinori .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2008, 2 (03) :99-101
[17]   HIGH-RESOLUTION X-RAY PHOTOEMISSION SPECTRUM OF VALENCE BANDS OF GOLD [J].
SHIRLEY, DA .
PHYSICAL REVIEW B, 1972, 5 (12) :4709-&
[18]   Observation of bulk HfO2 defects by spectroscopic ellipsometry [J].
Takeuchi, H ;
Ha, D ;
King, TJ .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (04) :1337-1341
[19]   CALCULATIONS OF ELECTRON INELASTIC MEAN FREE PATHS .5. DATA FOR 14 ORGANIC-COMPOUNDS OVER THE 50-2000 EV RANGE [J].
TANUMA, S ;
POWELL, CJ ;
PENN, DR .
SURFACE AND INTERFACE ANALYSIS, 1994, 21 (03) :165-176
[20]   Nonstoichiometry-Induced Carrier Modification in Gapless Type Atomic Switch Device Using Cu2S Mixed Conductor [J].
Tsuchiya, Takashi ;
Oyama, Yukiko ;
Miyoshi, Shogo ;
Yamaguchi, Shu .
APPLIED PHYSICS EXPRESS, 2009, 2 (05)