Lipase-catalyzed biodiesel production from soybean oil in ionic liquids

被引:197
作者
Ha, Sung Ho
Lan, Mai Ngoc
Lee, Sang Hyun
Hwang, Sung Mi
Koo, Yoon-Mo [1 ]
机构
[1] Inha Univ, Dept Biol Engn, Inchon 402751, South Korea
[2] Inha Univ, ERC Adv Biosparat Technol, Inchon 402751, South Korea
关键词
ionic liquids; biodiesel; fatty acid methyl ester (FAME); lipase; alcoholysis; transesterification;
D O I
10.1016/j.enzmictec.2007.03.017
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Production of biodiesel in ionic liquids through immobilized Candida antarctica lipase-catalyzed methanolysis of soybean oil was demonstrated. Among tested 23 ionic liquids, the highest fatty acid methyl esters (FAMEs) production after 12h at 50 degrees C was achieved in [Emim][TfO]. The production yield of 80% was eight times higher compared to the conventional solvent-free system. It was around 15% higher than the FAMEs production system using tert-butanol as an additive. The optimum substrate molar ratio of methanol to soybean oil for FAMEs production in [Emim][TfO] was found to be 4:1. Our results of high production yield in ionic liquids show that ionic liquids are potential reaction media for biodiesel production. (c) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码:480 / 483
页数:4
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