Patterning the Tips of Optical Fibers with Metallic Nanostructures Using Nanoskiving

被引:109
作者
Lipomi, Darren J. [1 ]
Martinez, Ramses V. [1 ]
Kats, Mikhail A. [2 ]
Kang, Sung H. [2 ]
Kim, Philseok [1 ,2 ]
Aizenberg, Joanna [1 ,2 ]
Capasso, Federico [2 ]
Whitesides, George M. [1 ]
机构
[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[2] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
基金
美国国家科学基金会;
关键词
Nanoskiving; nanofabrication; fiber optics; plasmonics; SERS; ultramicrotomy; ENHANCED RAMAN-SCATTERING; FABRICATION; LITHOGRAPHY; ARRAYS; ELECTRONICS; SURFACES; SENSORS; GOLD; NANOFABRICATION; NANOWIRES;
D O I
10.1021/nl103730g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Convenient and inexpensive methods to pattern the facets of optical fibers with metallic nanostructures would enable many applications. This communication reports a method to generate and transfer arrays of metallic nanostructures to the cleaved facets of optical fibers. The process relies on nanoskiving, in which an ultramicrotome, equipped with a diamond knife, sections epoxy nanostructures coated with thin metallic films and embedded in a block of epoxy. Sectioning produces arrays. of nanostructures embedded in thin epoxy slabs, which can be transferred Manually to the tips of optical fibers at a rate of approximately 2 min(-1), with 88% yield. Etching the epoxy matrices leaves arrays of nanostructures supported directly by the facets of the optical fibers. Examples of structures' transferred include gold crescents, rings, high-aspect-ratio concentric cylinders, and gratings of parallel nanowires.
引用
收藏
页码:632 / 636
页数:5
相关论文
共 43 条
[31]   Nanostructured plasmonic sensors [J].
Stewart, Matthew E. ;
Anderton, Christopher R. ;
Thompson, Lucas B. ;
Maria, Joana ;
Gray, Stephen K. ;
Rogers, John A. ;
Nuzzo, Ralph G. .
CHEMICAL REVIEWS, 2008, 108 (02) :494-521
[32]   Development of an integrated single-fiber SERS sensor [J].
Stokes, DL ;
Vo-Dinh, T .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :28-36
[33]   Fibre optic microarrays [J].
Walt, David R. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :38-50
[34]   Fabrication of surface plasmon resonators by nanoskiving single-crystalline gold microplates [J].
Wiley, Benjamin J. ;
Lipomi, Darren J. ;
Bao, Jiming ;
Capasso, Federico ;
Whitesides, George M. .
NANO LETTERS, 2008, 8 (09) :3023-3028
[35]   The future of lithography: SEMATECH Litho Forum 2008 [J].
Willson, C. Grant ;
Roman, Bernard J. .
ACS NANO, 2008, 2 (07) :1323-1328
[36]   A Decade of Step and Flash Imprint Lithography [J].
Willson, C. Grant .
JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2009, 22 (02) :147-153
[37]   Fiber-optic chemical sensors and biosensors [J].
Wolfbeis, Otto S. .
ANALYTICAL CHEMISTRY, 2008, 80 (12) :4269-4283
[38]   Complex optical surfaces formed by replica molding against elastomeric masters [J].
Xia, YN ;
Kim, E ;
Zhao, XM ;
Rogers, JA ;
Prentiss, M ;
Whitesides, GM .
SCIENCE, 1996, 273 (5273) :347-349
[39]   Fabrication of complex metallic nanostructures by nanoskiving [J].
Xu, Qiaobing ;
Rioux, Robert M. ;
Whitesides, George M. .
ACS NANO, 2007, 1 (03) :215-227
[40]   Fabrication of large-area patterned nanostructures for optical applications by nanoskiving [J].
Xu, Qiaobing ;
Bao, Jiming ;
Rioux, Robert M. ;
Perez-Castillejos, Raquel ;
Capasso, Federico ;
Whitesides, George M. .
NANO LETTERS, 2007, 7 (09) :2800-2805