A non-equilibrium free energy theorem for deterministic systems

被引：76

作者：

Evans, DJ ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

MOLECULAR PHYSICS | 2003年 / 101卷 / 10期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1080/0026897031000085173

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Jarzynski and Crooks have recently shown that equilibrium free energy differences can be computed from non-equilibrium thermodynamic path integrals. In the present paper we give a new derivation of this extraordinary relation. Our derivation which is valid for time reversible deterministic systems highlights the close relationship between the non-equilibrium free energy theorems and the fluctuation theorem.

引用

页码：1551 / 1554

页数：4

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