Nanocrystallized tetragonal metastable ZrO2 thin films deposited by metal-organic chemical vapor deposition for 3D capacitors

被引:30
作者
Brunet, M. [1 ]
Kotb, H. Mafhoz [2 ]
Bouscayrol, L. [1 ]
Scheid, E. [1 ]
Andrieux, M. [3 ]
Legros, C. [3 ]
Schamm-Chardon, S. [4 ]
机构
[1] Univ Toulouse, CNRS, LAAS, F-31077 Toulouse, France
[2] Univ Assiut, Dept Phys, Fac Sci, Assiut 71516, Egypt
[3] Univ Paris 11, LEMHE ICMMO, CNRS, UMR 8182, F-91405 Orsay, France
[4] Univ Toulouse, NMat Grp, CEMES CNRS, F-31055 Toulouse, France
关键词
Metal organic chemical vapor deposition; Zirconium oxide; Tetragonal; High dielectric constant; 3D capacitors; Transmission electron microscopy; Electrical properties and measurements; ATOMIC LAYER DEPOSITION; ELECTRICAL-PROPERTIES; HIGH-DENSITY; ZIRCONIA; SPECTRA; MOCVD; PURE;
D O I
10.1016/j.tsf.2011.03.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZrO2 is a potential candidate for the realization of 3D capacitors on silicon for future Systems-on-Chip. This paper reports on the deposition of ZrO2 thin films by metal-organic chemical vapor deposition on planar and 3D structures. Physico-chemical as well as electrical properties of the films are investigated. It is shown that the change of phase and microstructure of the film due to annealing at 900 degrees C under O-2 impacts directly on the electrical performance of the capacitors. Capacitance densities are 2 nF/mm(2) for planar capacitors and reach 8 nF/mm(2) for capacitors with pores etched in silicon with a 4:1 aspect ratio. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:5638 / 5644
页数:7
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