Lewis acid mediated domino allylation of diallylsilane to α,β-unsaturated ketones

被引：10

作者：

Akiyama, T ^{[1
]}

Asayama, K ^{[1
]}

Fujiyoshi, S ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 22期

关键词：

D O I：

10.1039/a807640e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On treatment of diallyldiisopropylsilane and alpha,beta-unsaturated ketones with BF3. OEt2, 1,4-addition of an allyl moiety and subsequent intramolecular allylation onto the beta-silyl carbocation intermediate furnished domino allylation products. Oxidative cleavage of the carbon-silicon bond furnished bis-homoallylic alcohols in good yields.

引用

页码：3655 / 3656

页数：2

共 36 条

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