A quarter of a century of explorations in organozirconium chemistry

被引：102

作者：

Negishi, E ^{[1
]}

机构：

[1] Purdue Univ, Herbert C Brown Labs Chem, W Lafayette, IN 47907 USA

来源：

DALTON TRANSACTIONS | 2005年 / 05期

关键词：

D O I：

10.1039/b417134a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Systematic explorations of organozirconium chemistry over the past quarter of a century have led to the discoveries and development as well as structural and mechanistic clarifications of novel Zr-catalyzed and -promoted carbon-carbon bond-forming reactions including (i) Ni- or Pd-catalyzed cross-coupling reaction of organozirconiums, (ii) Zr-catalyzed carboalumination of alkynes, (iii) Zr-catalyzed asymmetric carboalumination of alkenes, (iv) generation and carbometallative ring expansion of zirconacyclopropanes and zirconacyclopropenes and a myriad of their transformations and (v) various organozirconium migratory insertion reactions.

引用

页码：827 / 848

页数：22

共 233 条

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