Effect of precursor concentration and bath temperature on the growth of chemical bath deposited tin sulphide thin films

被引:58
作者
Jayasree, Y. [1 ]
Chalapathi, U. [1 ]
Bhaskar, P. Uday [1 ]
Raja, V. Sundara [1 ]
机构
[1] Sri Venkateswara Univ, Dept Phys, Solar Energy Lab, Tirupati 517502, Andhra Pradesh, India
关键词
SnS; Chemical bath deposition; Solar cell absorber; Triethanolamine; XRD; Band gap; ELECTROCHEMICAL DEPOSITION; ELECTRICAL-PROPERTIES; SNS;
D O I
10.1016/j.apsusc.2011.10.124
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SnS is a promising candidate for a low-cost, non-toxic solar cell absorber layer. Tin sulphide thin films have been deposited by chemical bath deposition technique from a solution containing stannous chloride, thioacetamide, ammonia and triethanolamine (TEA). The effects of concentration of tin salt, triethanolamine and bath temperature on the growth of tin sulphide films have been investigated in order to optimize the growth conditions to obtain tin monosulphide (SnS) films. SnS films obtained under optimized conditions were found to be polycrystalline in nature with orthorhombic structure. The optical band gap of these films was found to be 1.5 eV. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2732 / 2740
页数:9
相关论文
共 22 条
[1]   Chemically deposited tin sulphide [J].
Akkari, A. ;
Guasch, C. ;
Kamoun-Turki, N. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 490 (1-2) :180-183
[2]   Polymorphic tin sulfide thin films of zinc blende and orthorhombic structures by chemical deposition [J].
Avellaneda, David ;
Nair, M. T. S. ;
Nair, P. K. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (07) :D517-D525
[3]   Deposition of tin sulfide thin films from tin(IV) thiolate precursors [J].
Barone, G ;
Hibbert, TG ;
Mahon, MF ;
Molloy, KC ;
Price, LS ;
Parkin, IP ;
Hardy, AME ;
Field, MN .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (02) :464-468
[4]   Structural, optical, and electrical properties of tin sulfide thin films grown by spray pyrolysis [J].
Calixto-Rodriguez, M. ;
Martinez, H. ;
Sanchez-Juarez, A. ;
Campos-Alvarez, J. ;
Tiburcio-Silver, A. ;
Calixto, M. E. .
THIN SOLID FILMS, 2009, 517 (07) :2497-2499
[5]   Optical properties of thermally evaporated SnS thin films [J].
El-Nahass, MM ;
Zeyada, HM ;
Aziz, MS ;
El-Ghamaz, NA .
OPTICAL MATERIALS, 2002, 20 (03) :159-170
[6]   Synthesis and characterization of tin sulphide thin films grown by chemical bath deposition technique [J].
Hankare, P. P. ;
Jadhav, A. V. ;
Chate, P. A. ;
Rathod, K. C. ;
Chavan, P. A. ;
Ingole, S. A. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 463 (1-2) :581-584
[7]   SnS thin-films by RF sputtering at room temperature [J].
Hartman, Katy ;
Johnson, J. L. ;
Bertoni, Mariana I. ;
Recht, Daniel ;
Aziz, Michael J. ;
Scarpulla, Michael A. ;
Buonassisi, Tonio .
THIN SOLID FILMS, 2011, 519 (21) :7421-7424
[8]   Electrochemical deposition of SnS thin films [J].
Ichimura, M ;
Takeuchi, K ;
Ono, Y ;
Arai, E .
THIN SOLID FILMS, 2000, 361 :98-101
[10]   Tin Sulfide Thin Films by Pulse Electrodeposition: Structural, Morphological, and Optical Properties [J].
Mathews, N. R. ;
Anaya, Hiran B. M. ;
Cortes-Jacome, M. A. ;
Angeles-Chavez, C. ;
Toledo-Antonio, J. A. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (03) :H337-H341