Water-soluble sacrificial layers for surface micromachining

被引:167
作者
Linder, V [1 ]
Gates, BD [1 ]
Ryan, D [1 ]
Parviz, BA [1 ]
Whitesides, GM [1 ]
机构
[1] Harvard Univ, Sch Med, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
关键词
microelectromechanical systems; polymers; sacrificial layers; spin coating; surface micromachining;
D O I
10.1002/smll.200400159
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This manuscript describes the use of water-soluble polymers for use as sacrificial layers in surface micromachining. Water-soluble polymers have two attractive characteristics for this application: 1) They can be deposited conveniently by spin-coating, and the solvent removed at a low temperature (95-150 degrees C), and 2) the resulting layer can be dissolved in water; no corrosive reagents or organic solvents are required. This technique is therefore compatible with a number of fragile materials, such as organic polymers, metal oxides and metals-materials that might be damaged during typical surface micromachining processes. The carboxylic acid groups of one polymer-poly (acrylic acid) (PAA)-can be transformed by reversible ion-exchange from water-soluble (Na+ counterion) to water-insoluble (Ca2+ counterion) forms. The use of PAA and dextran polymers as sacrificial materials is a useful technique for the fabrication of microstructures: Examples include metallic structures formed by the electrodeposition of nickel, and freestanding, polymeric structures formed by photolithography.
引用
收藏
页码:730 / 736
页数:7
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