Octahedral ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(isopropyl)oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2(PMe3)2(FcPN)] and fac-[RuCl2(dppm)(FcPN)] (dppm = bis(diphenylphosphino)methane)

被引：9

作者：

Gimeno, J ^{[1
]}

Lastra, E

Madrigal, C

Graiff, C

Tiripicchio, A

机构：

[1] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan,Unidad Asociada, Inst Univ Quim Organomet Enrique Moles,CSIC, Oviedo 33006, Spain

[2] Univ Parma, Dipartimento Chim Gen & Inorgan, Ctr Studio Strutturist Diffrattometr, CNR, I-43100 Parma, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

关键词：

ruthenium(II); chiral ligand; ferrocenylphosphine; ferrocenyloxazoline;

D O I：

10.1016/S0022-328X(01)00949-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Octahedral ruthenium(II) complexes containing the chiral ligand (4S)-2-[(S-p)-2-(diphenylphosphino)ferrocenyl]-4-(isopropyl)oxazoline (FcPN) have been prepared from complex [RuCl2(PPh3)(FcPN)] (1) via phosphine exchange reactions. Complex I reacts with PMe3, PMe2Ph, bis(diphenylphosphino)methane (dppm) and 1,2-bis(diphenylphosphino)ethane (dppe) affording in good yield the complexes [RuCl2L2(FcPN)] (L = PMe3 (2a), PMe2Ph (2b)) and [RuCl2(L-L)(FcPN)] (L-L = dppm. (3a), dppe (4)). The processes are stereoselective giving rise to the thermodynamically stable fac isomers. The kinetically controlled formation of the mer isomer [RuCl2(dppm)(FcPN)] (3b) is also described. Structural characterization of the complexes has been carried out by means of H-1-, P-31{H-1}- and C-13{H-1}-NMR spectroscopy and the crystal structures of the complexes 2a and 3a have been determined by X-ray diffraction methods. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：463 / 468

页数：6

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