Silver-Catalyzed 2-Pyridyl Arylation of Pyridine N-Oxides with Arylboronic Acids at Room Temperature

被引：39

作者：

Mai, Wenpeng ^{[1
]}

Yuan, Jinwei ^{[1
]}

Li, Zhicheng ^{[1
]}

Sun, Gangchun ^{[1
]}

Qu, Lingbo ^{[1
]}

机构：

[1] Henan Univ Technol, Chem & Chem Engn Sch, Zhengzhou Henan 450001, Peoples R China

来源：

SYNLETT | 2012年 / 23卷 / 01期

关键词：

silver; pyridine N-oxides; arylation; C-H ACTIVATION; BOND FORMATION; UNACTIVATED ARENES; SODIUM PERSULFATE; PALLADIUM; FUNCTIONALIZATION; ALKENYLATION; OLEFINATION; ANILIDES; CLEAVAGE;

D O I：

10.1055/s-0031-1290088

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel direct arylation of pyridine N-oxides with arylboronic acids through C-H functionalization has been developed. This new reaction is performed at room temperature using catalytic silver(I) nitrate in the presence of potassium persulfate and give 2-pyridyl arylation derivatives of pyridine N-oxides.

引用

页码：145 / 149

页数：5

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