2-(Trimethylsilyl)ethanesulfonyl amide as a new ammonia equivalent for palladium-catalyzed amination of aryl halides

被引：20

作者：

Anjanappa, Prakash ^{[1
]}

Mullick, Dibakar ^{[1
]}

Selvakumar, Kumaravel ^{[1
]}

Sivakumar, Manickam ^{[2
,3
]}

机构：

[1] Syngene Int Ltd, Synthet Chem, Bommasandra Ind Area, Bangalore 560099, Karnataka, India

[2] Bharathidasan Univ, Bharathidasan Inst Technol, Dept Pharmaceut Engn & Technol, Tiruchirappalli 620024, India

[3] Univ Nottingham, Sch Chem & Environm Engn, Semenyih 43500, Malaysia

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 31期

关键词：

palladium catalysis; ammonia surrogates; cross-coupling; 2-(trimethylsilyl)ethanesulfonyl amide;

D O I：

10.1016/j.tetlet.2008.05.099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-(Trimethylsilyl)ethanesulfonyl amide (SES-NH2) is an ammonia equivalent for the palladium-catalyzed amination of aryl bromides and aryl chlorides. Using these amine derivatives, it has been observed that anilines and anilines with sensitive functional groups can be readily prepared. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：4585 / 4587

页数：3

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