Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

被引：175

作者：

Burks, Heather E. ^{[1
]}

Morken, James P. ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 45期

关键词：

D O I：

10.1039/b707779c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in asymmetric organic synthesis.

引用

页码：4717 / 4725

页数：9

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