New monodentate chiral phosphine 2,6-dimethyl-9-phenyl-9-phosphabicyclo[3.3.1]nonane(9-PBN): Application to asymmetric allylic substitution reaction

被引：42

作者：

Hamada, Y ^{[1
]}

Seto, N ^{[1
]}

Ohmori, H ^{[1
]}

Hatano, K ^{[1
]}

机构：

[1] NAGOYA CITY UNIV,FAC PHARMACEUT SCI,MIZUHO KU,NAGOYA,AICHI 467,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 42期

关键词：

D O I：

10.1016/0040-4039(96)01718-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New monodentate chiral phosphines. (+)- and (-)-2,6-dimethyl-9-phenyl-9-phosphabicyclo[3.3.1]nonanes ((+)- and (-)-9-PBNs), were prepared from 1,5-dimethyl-1,5-cyclooctadiene, and their application to the asymmetric allylic substitution reaction proved the utility of 9-PBNs as chiral phosphine ligands. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7565 / 7568

页数：4

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