Growth mechanism of TiN film on dielectric films and the effects on the work function

被引:32
作者
Choi, K
Lysaght, P
Alshareef, H
Huffman, C
Wen, HC
Harris, R
Luan, H
Hung, PY
Sparks, C
Cruz, M
Matthews, K
Majhi, P
Lee, BH
机构
[1] SEMATECH, Austin, TX 78741 USA
[2] Texas Instruments Inc, Austin, TX 78741 USA
[3] AMD, Austin, TX 78741 USA
[4] Infineon, Austin, TX 78741 USA
[5] Philips, Austin, TX 78741 USA
[6] IBM Corp, Austin, TX 78741 USA
关键词
MOSFET; metal gate electrode; high-k gate dielectric; TiN; atomic layer deposition; work function;
D O I
10.1016/j.tsf.2004.11.239
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have investigated the growth mechanism of ALD-TiN film on different dielectrics and the resulting effective work function value. TiN nucleation rate and growth rate are found to be dependent on the dielectric films. TiN growth mechanism changed from 3-D type on SiO2, to layer-by-layer type on HfO2,. The minimum TiN thickness required for a complete surface coverage varies according to the growth mechanism. Capacitor (MOSCAP) characterization revealed that the effective work function of TiN is dependent not only on dielectric films but also on the TiN thickness. The behavior of work function and fixed charge correlated with the growth mechanism of TiN on dielectric films. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:141 / 144
页数:4
相关论文
共 12 条
[1]  
CHOI K, 2004, WOE11 C
[2]  
Datta S, 2003, 2003 IEEE INTERNATIONAL ELECTRON DEVICES MEETING, TECHNICAL DIGEST, P653
[3]  
GEORGE B, 2004, IEEE SISC C
[4]   Atomic layer deposition of metal and nitride thin films: Current research efforts and applications for semiconductor device processing [J].
Kim, H .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2003, 21 (06) :2231-2261
[5]   Low temperature catalytic formation of Si-based metal-oxide-semiconductor structure [J].
Kobayashi, H ;
Yuasa, T ;
Nakato, Y ;
Yoneda, K ;
Todokoro, Y .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (07) :4124-4128
[6]   Metal gates for advanced CMOS technology [J].
Maiti, B ;
Tobin, PJ .
MICROELECTRONIC DEVICE TECHNOLOGY III, 1999, 3881 :46-57
[7]   Impact of atomic-layer-deposited TiN on the gate oxide quality of W/TiN/SiO2/Si metal-oxide-semiconductor structures [J].
Park, DG ;
Lim, KY ;
Cho, HJ ;
Cha, TH ;
Yeo, IS ;
Roh, JS ;
Park, JW .
APPLIED PHYSICS LETTERS, 2002, 80 (14) :2514-2516
[8]   Fermi-level pinning induced thermal instability in the effective work function of TaN in TaN/SiO2 gate stack [J].
Ren, C ;
Yu, HY ;
Kang, JF ;
Hou, YT ;
Li, ME ;
Wang, WD ;
Chan, DSH ;
Kwong, DL .
IEEE ELECTRON DEVICE LETTERS, 2004, 25 (03) :123-125
[9]   High-resolution work function imaging of single grains of semiconductor surfaces [J].
Sadewasser, S ;
Glatzel, T ;
Rusu, M ;
Jäger-Waldau, A ;
Lux-Steiner, MC .
APPLIED PHYSICS LETTERS, 2002, 80 (16) :2979-2981
[10]   On the thermal stability of atomic layer deposited TiN as gate electrode in MOS devices [J].
Westlinder, J ;
Schram, T ;
Pantisano, L ;
Cartier, E ;
Kerber, A ;
Lujan, GS ;
Olsson, J ;
Groeseneken, G .
IEEE ELECTRON DEVICE LETTERS, 2003, 24 (09) :550-552