On the thermal stability of atomic layer deposited TiN as gate electrode in MOS devices

The work function of ALD TiN was found to be above 5 eV after RTP annealing below 800 degreesC in nitrogen atmosphere, while higher annealing temperatures cause a drop in work function by about 0.3-0.5 eV. The effect was found for TiN metal gates on both SiO2 and Al2O3 gate dielectrics in MOS-capacitors and was seen in C-V as well as in I-V measurements. On the contrary, annealing Of SiO2 capacitors in oxygen-enriched N-2 atmosphere increased the work function. A variation in EOT of less than 2 Angstrom was demonstrated for the various annealing temperatures, concluding that the ALD TiN is stable in contact with the different dielectric materials. However, the decrease in work function that is found in this investigation may implicate that ALD TiN is less suitable as a metal, gate for pMOSFETs.