Iron-Catalyzed Suzuki-Miyaura Coupling of Alkyl Halides

被引：273

作者：

Hatakeyama, Takuji ^{[1
]}

Hashimoto, Toru ^{[1
,2
]}

Kondo, Yoshiyuki ^{[1
,2
]}

Fujiwara, Yuichi ^{[1
,2
]}

Seike, Hirofumi ^{[1
]}

Takaya, Hikaru ^{[1
]}

Tamada, Yoshinori

Ono, Teruo

Nakamura, Masaharu ^{[1
]}

机构：

[1] Kyoto Univ, Int Res Ctr Elements Sci, Inst Chem Res, IRCELS, Kyoto 6110011, Japan

[2] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Grad Sch Engn, Kyoto 6110011, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 31期

基金：

日本学术振兴会;

关键词：

ARYL GRIGNARD-REAGENTS; LIVING RADICAL POLYMERIZATION; PARAMAGNETIC-SUSCEPTIBILITY; ORGANOBORON COMPOUNDS; ORGANIC-SYNTHESIS; BORONIC ACIDS; PHOSPHATES; ALKENYL; COBALT; REACTIVITY;

D O I：

10.1021/ja103973a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of novel iron(II) chloride-diphosphine complexes and magnesium bromide, lithium arylborates react with primary and secondary alkyl halides to give the corresponding coupling products in good to excellent yields. High functional group compatibility is also demonstrated in the reactions of substrates possessing reactive substituents, such as alkoxycarbonyl, cyano, and carbonyl groups.

引用

页码：10674 / 10676

页数：3

共 61 条

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