Microporous polymer network films covalently bound to gold electrodes

被引:29
作者
Becker, Daniel [1 ]
Heidary, Nina [2 ,3 ]
Horch, Marius [2 ]
Gernert, Ulrich [4 ]
Zebger, Ingo [2 ]
Schmidt, Johannes [1 ]
Fischer, Anna [2 ,3 ]
Thomas, Arne [1 ]
机构
[1] Tech Univ Berlin, Dept Chem Funct Mat, D-10623 Berlin, Germany
[2] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany
[3] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany
[4] Tech Univ Berlin, Ctr Elect Microscopy ZELMI, D-10623 Berlin, Germany
基金
欧洲研究理事会;
关键词
CARBON-DIOXIDE CAPTURE; ORGANIC FRAMEWORK; CONJUGATED POLYMERS; GAS-STORAGE; CATALYSTS;
D O I
10.1039/c4cc09637a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.
引用
收藏
页码:4283 / 4286
页数:4
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