Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework;: syntheses and structures of [LiCl{ButNHP(μ-NBut)2PNH(2-py)}3] and [{ButNP(μ-NBut)2PN(2-py)} Li2•{Li(ButN)2P}]

被引：8

作者：

Bond, AD ^{[1
]}

Doyle, EL ^{[1
]}

Kidd, SJ ^{[1
]}

Woods, AD ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b010093p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The neutral ligand [(BuNHP)-N-t(mu -NBut)(2)PNH(2-py)] and its dilithiate [{(BuNP)-N-t(mu -NBut)(2)PN(2-py)}Li-2] exhibit a parallel ability to coordinate cations and anions, as revealed in the structures of the tris-solvate [LiCl{(BuNHP)-N-t(mu -NBut)(2)PNH(2-py)}(3)] 1 and the unusual co-complex [{(BuNP)-N-t(mu -NBut)(2)PN(2-py)}Li-2. {Li((BuN)-N-t)(2)P}] 2.

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收藏

页码：777 / 778

页数：2

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