Studying the local chemical environment of sulfur atoms at buried interfaces in CdS/ZnSe superlattices

被引:10
作者
Heske, C
Groh, U
Fuchs, O
Weinhardt, L
Umbach, E
Grün, M
Petillon, S
Dinger, A
Klingshirn, C
Szuszkiewicz, W
Fleszar, A
机构
[1] Univ Wurzburg, D-97074 Wurzburg, Germany
[2] Univ Karlsruhe, Inst Angew Phys, D-76128 Karlsruhe, Germany
[3] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
关键词
D O I
10.1063/1.1609235
中图分类号
O59 [应用物理学];
学科分类号
摘要
Soft x-ray emission spectroscopy has been employed to study the local chemical environment of sulfur atoms in sulfide II-VI semiconductors (ZnS, CdS, HgS) and CdS/ZnSe superlattices. By using fluorescence transitions involving metal d-state-derived valence bands and S 2p core holes, a distinction between S-Zn and S-Cd bonds in the superlattices can be made. We find that, in addition to the expected S-Cd bonds, interfacial S-Zn bonds are present in superlattices grown at 170 degreesC, and that the amount of S-Zn bonds significantly increases for growth at 300 degreesC due to interface intermixing. (C) 2003 American Institute of Physics.
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收藏
页码:2360 / 2362
页数:3
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