Manganese trifluoroacetoxycarbene complexes are convenient intermediates in the synthesis of cyclic enediynes

被引：17

作者：

Casey, CP ^{[1
]}

Dzwiniel, TL ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 25期

关键词：

D O I：

10.1021/om030561+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoroacetoxycarbene complexes generated from reaction of stable manganese acyl complexes with trifluoroacetic anhydride are convenient alternatives to thermally sensitive manganese carbyne complexes in reactions with diynes that lead eventually to free cyclic enediynes. In situ reaction of these trifluoroacetoxycarbene complexes with alkynyl copper intermediates generated from diynes, CuBr, and NEt(i-Pr)(2) led to the isolation of cyclic enediynes via intermediate linked alkynylcarbene complexes and manganese enediyne complexes.

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页码：5285 / 5290

页数：6

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