Self-assembly of a nanoscopic prism via a new organometallic Pt3 acceptor and its fluorescent detection of nitroaromatics

被引:137
作者
Ghosh, Sushobhan [1 ]
Mukherjee, Partha Sarathi [1 ]
机构
[1] Indian Inst Sci, Dept Phys & Inorgan Chem, Bangalore 560012, Karnataka, India
关键词
D O I
10.1021/om701082y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A nanoscale-sized cage with a trigonal prismatic shape is prepared by coordination-driven self-assembly of a predesigned organometallic Pt-3 acceptor with an organic clip-type ligand. This trigonal prism is fluorescent and undergoes efficient fluorescence quenching by nitroaromatics, which are the chemical signatures of many explosives.
引用
收藏
页码:316 / 319
页数:4
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