Design and synthesis of a Pt(II) nanoscopic trigonal bipyramidal cage using a new tripodal ester-containing ligand

被引：10

作者：

Ghosh, Sushobhan ^{[1
]}

Mukherjee, Partha Sarathi ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 52期

关键词：

supramolecular assemblies; tripod ligand; TBP cage; electrospray ionization;

D O I：

10.1016/j.tetlet.2006.10.105

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formation of a Pt(II) nanoscopic trigonal bipyramidal cage (TBP) containing a new tripodal linker with ester functionality is achieved by self-assembly. The new tripod ligand and the cage were characterized by multinuclear NMR and electrospray ionization mass spectroscopy. Energy minimized simulation of the cage yielded a pseudo TBP shape with an internal diameter of 2 nm. (c) 2006 Elsevier Ltd. All rights reserved.

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收藏

页码：9297 / 9300

页数：4

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