Lithium perchlorate-catalyzed three-component coupling:: A facile and general method for the synthesis of α-aminophosphonates under solvent-free conditions

被引：80

作者：

Azizi, N ^{[1
]}

Saidi, MR ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 23期

关键词：

D O I：

10.1002/ejoc.200300479

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, efficient, and general method has been developed for the synthesis of alpha-aminophosphonates in the presence of solid lithium perchlorate under solvent-free conditions. Thus secondary and tertiary alpha-aminophosphonates were synthesized relatively quickly in good yields at room temperature. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：4630 / 4633

页数：4

共 28 条

[11] BIOLOGICAL-ACTIVITY OF AMINOPHOSPHONIC ACIDS
KAFARSKI, P
LEJCZAK, B
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1991, 63 (1-2) : 193 - 215
[12] Kudzin ZH, 1997, SYNTHESIS-STUTTGART, P44
[13] Kukhar V. P., 1987, Russ. Chem. Rev., V56, P859
[14] LASCHAT S, 1992, SYNTHESIS-STUTTGART, P90
[15] Lanthanide triflate-catalyzed three component synthesis of α-amino phosphonates in ionic liquids.: A catalyst reactivity and reusability study
Lee, SG
Park, JH
Kang, J
Lee, JK
[J]. CHEMICAL COMMUNICATIONS, 2001, (17) : 1698 - 1699
[16] Facile synthesis of α-amino phosphonates in water using a Lewis acid-surfactant-combined catalyst
Manabe, K
Kobayashi, S
[J]. CHEMICAL COMMUNICATIONS, 2000, (08) : 669 - 670
[17] Aminosilylation of aldehydes mediated by lithium perchlorate:: novel method for synthesis of α-silylamines
Naimi-Jamal, MR
Mojtahedi, MM
Ipaktschi, J
Saidi, MR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (24): : 3709 - 3711
[18] One-pot synthesis of α-amino phosphonates from aldehydes using lanthanide triflate as a catalyst
Qian, CT
Huang, TS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (12) : 4125 - 4128
[19] General procedure for the synthesis of α-amino phosphonates from aldehydes and ketones using indium(III) chloride as a catalyst
Ranu, BC
Hajra, A
Jana, U
[J]. ORGANIC LETTERS, 1999, 1 (08) : 1141 - 1143
[20] Highly diastereoselective aminoalkylation of naphthols with chiral amines mediated by lithium perchlorate solution in diethyl ether
Saidi, MR
Azizi, N
[J]. TETRAHEDRON-ASYMMETRY, 2003, 14 (03) : 389 - 392

← 1 2 3 →