Synthesis of [2,3,4,5,6-2H5]phenyl glucosinolate

被引：6

作者：

Bialecki, Jason B. ^{[1
]}

Ruzicka, Josef ^{[1
]}

Attygalle, Athula B. ^{[1
]}

机构：

[1] Stevens Inst Technol, Ctr Mass Spectrometry, Dept Chem & Chem Biol, Hoboken, NJ 07030 USA

来源：

JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2007年 / 50卷 / 7-8期

关键词：

glucosinolates; phenyl glucosinolate; collision-induced dissociation (CID); internal standard; electrospray-ionization mass spectrometry;

D O I：

10.1002/jlcr.1407

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Starting from commercially available [2,3,4,5,6-H-2(5)]benzoic acid, [2,3,4,5,6-H-2(5)]phenyl glucosinolate was synthesized. Under negative-ion electrospray-ionization mass spectrometric conditions, this compound affords a peak at m/z 399. Since this m/z value is not known from the ions derived from natural glucosinolates, the [2,3,4,5,6-H-2(6)]phenyl glucosinolate reported here is useful as an internal standard for the quantification of glucosinolates by negative-ion mass spectrometry (MS) and liquid chromatography (LC)/MS techniques. Copyright (c) 2007 John Wiley & Sons, Ltd.

引用

页码：711 / 715

页数：5

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