Enantioselective Diethylzinc Addition to Aromatic Aldehydes Catalyzed by Novel Ti(IV) Complex of Three-Dentate Chiral Sulfonamide Ligands

被引：5

作者：

Dabiri, Minoo ^{[1
]}

Salehi, Peyman ^{[2
]}

Heydari, Seddigheh ^{[1
]}

Kozehgary, Gholamreza ^{[1
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, Fac Sci, GC, Tehran, Iran

[2] Shahid Beheshti Univ, Dept Phytochem, Med Plants & Drugs Res Inst, GC, Tehran, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 24期

关键词：

Aldehydes; diethylzinc; enantioselectivity; sulfonamide alcohols; DIALKYLZINC; REAGENTS; ALCOHOLS;

D O I：

10.1080/00397910902900688

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of several novel three-dentate sulfonamide alcohol ligands is described, starting from camphorsulfonyl chloride. The influence of temperature and ligand structure on the asymmetric addition of dietylzinc to aromatic aldehydes has been studied. Enantioselectivities up to 76% have been obtained.

引用

页码：4350 / 4361

页数：12

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