The asymmetric hydrogenation of imines using tridentate C-2 diphosphine complexes of iridium(I) and rhodium(I).

被引：102

作者：

Sablong, R ^{[1
]}

Osborn, JA ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CNRS,LAB CHIM MET TRANSIT & CATALYSE,INST BEL,F-67070 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 28期

关键词：

D O I：

10.1016/0040-4039(96)00967-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the synthesis of [M(PNP)(diene)](+) complexes (M = Ir or Rh; diene = COD or NBD), where PNP represents a tridentate diphosphine ligand of C-2 symmetry. These complexes are active catalysts for the hydrogenation of imines. Reduction of prochiral imines in the presence of chiral ligands leads to the corresponding amines with 7 to 55% ee. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4937 / 4940

页数：4

共 13 条

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