Solid phase chemistry at a modified cathode surface. First synthesis of a polyamine precursor

被引：19

作者：

Marchand, G ^{[1
]}

Pilard, JF ^{[1
]}

Simonet, J ^{[1
]}

机构：

[1] Univ Rennes 1, Lab Electrochim Mol & Macromol, F-35042 Rennes, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 06期

关键词：

polyamines; solid phase synthesis; polythiophene; modified cathode; electrochemical bond cleavage;

D O I：

10.1016/S0040-4039(99)02217-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a polyamine precursor was performed at a modified electrode interface. The chemical behaviour of the polythiophene matrix appeared identical to that of polystyrene beads. The target molecule, obtained with good yield, was released from the solid support by cathodic S-N bond scission, using the conducting properties of the polymer. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：883 / 885

页数：3

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