The effect of the H2 flow rate on the structure and optical properties of TiO2 films deposited by inductively coupled plasma assisted chemical vapor deposition

被引:3
作者
Jang, D. S. [1 ]
Lee, H. Y. [1 ]
Lee, J. J. [1 ]
机构
[1] Seoul Natl Univ, Coll Engn, Sch Mat Sci & Engn, Plasma Surface Engn Lab, Seoul 151742, South Korea
关键词
Titanium oxide; Inductively coupled plasma (ICP); Hydrogen dilution; Phase transition; PHOTOCATALYTIC ACTIVITY; THIN-FILMS; SILICON; TEMPERATURE; GROWTH;
D O I
10.1016/j.tsf.2009.01.125
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The optical and photocatalytic properties of TiO2 are closely related to crystalline structures, such as rutile and anatase. In this paper, TiO2 films were produced by inductively coupled plasma (ICP) assisted chemical vapor deposition (CVD) without extra heating of the substrate, and the effect Of H-2 addition on the structure and optical properties of the films was investigated. After increasing the partial pressure of H-2, the structure of the TiO2 films changed from anatase to rutile, which usually appears at high temperatures (>600 degrees C). The light transmittance decreased with increasing the H-2 flow rate due to the increased surface roughness. The photocatalytic activity of the anatase TiO2 film was better than that of the rutile TiO2 film. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:3967 / 3970
页数:4
相关论文
共 10 条
[1]   Influence of annealing temperature on the properties of titanium oxide thin film [J].
Hou, YQ ;
Zhuang, DM ;
Zhang, G ;
Zhao, M ;
Wu, MS .
APPLIED SURFACE SCIENCE, 2003, 218 (1-4) :97-105
[2]   Effect of hydrogen on the low-temperature growth of polycrystalline silicon film deposited by SiCl4/H2 [J].
Huang, Rui ;
Lin, Xuanying ;
Huang, Wenyong ;
Yao, Ruohe ;
Yu, Yunpeng ;
Lin, Kuixun ;
Wei, Junhong ;
Zhu, Zusong .
THIN SOLID FILMS, 2006, 513 (1-2) :380-384
[3]   Characterization of a TiO2 photocatalyst film deposited by CVD and its photocatalytic activity [J].
Jung, SC ;
Kim, BH ;
Kim, SJ ;
Imaishi, N ;
Cho, YI .
CHEMICAL VAPOR DEPOSITION, 2005, 11 (03) :137-141
[4]   Effects of interfacial layer growth on the electrical characteristics of thin titanium oxide films on silicon [J].
Lee, BH ;
Jeon, Y ;
Zawadzki, K ;
Qi, WJ ;
Lee, J .
APPLIED PHYSICS LETTERS, 1999, 74 (21) :3143-3145
[5]   PHOTOCATALYSIS ON TIO2 SURFACES - PRINCIPLES, MECHANISMS, AND SELECTED RESULTS [J].
LINSEBIGLER, AL ;
LU, GQ ;
YATES, JT .
CHEMICAL REVIEWS, 1995, 95 (03) :735-758
[6]   The effect of O2 partial pressure on the structure and photocatalytic property of TiO2 films prepared by sputtering [J].
Liu, BS ;
Zhao, XJ ;
Zhao, QN ;
Li, CL ;
He, X .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 90 (01) :207-212
[7]   On the structural properties and optical transmittance of TiO2 r.f. sputtered thin films [J].
Mardare, D ;
Tasca, M ;
Delibas, M ;
Rusu, GI .
APPLIED SURFACE SCIENCE, 2000, 156 (1-4) :200-206
[8]   DETERMINATION OF SURFACE-ROUGHNESS AND OPTICAL-CONSTANTS OF INHOMOGENEOUS AMORPHOUS-SILICON FILMS [J].
SWANEPOEL, R .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1984, 17 (10) :896-903
[9]   Preparation of a TiO2 based multiple layer thin film photocatalyst [J].
Yasumori, A ;
Ishizu, K ;
Hayashi, S ;
Okada, K .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (11) :2521-2524
[10]   Photocatalytic activity of nanostructured TiO2 thin films prepared by dc magnetron sputtering method [J].
Zheng, SK ;
Wang, TM ;
Xiang, G ;
Wang, C .
VACUUM, 2001, 62 (04) :361-366