Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

被引：77

作者：

Ramos, Alberto ^{[1
]}

Lough, Alan J. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; PHOSPHONIUM; PHOSPHINES; HYDROGEN; BORANE; ELECTROCHEMISTRY; REACTIVITY; CLEAVAGE; CARBENE;

D O I：

10.1039/b819525k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono- and bis-phosphinoferrocenes are shown to react as frustrated Lewis pairs (FLPs) to effect nucleophilic aromatic substitution on B(C6F5)(3) and/or activate H-2 to form ferrocenylphosphonium borates.

引用

页码：1118 / 1120

页数：3

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