Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct

被引：515

作者：

Spies, Patrick

Erker, Gerhard

Kehr, Gerald

Bergander, Klaus

Froehlich, Roland

Grimme, Stefan

Stephan, Douglas W.

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 47期

关键词：

HYDROGENATION; PHOSPHINES;

D O I：

10.1039/b710475h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A four-membered cyclic intramolecular phosphane-borane adduct activates dihydrogen to yield the respective ethylenebridged zwitterionic phosphonium-hydridoborate system, which reduces benzaldehyde.

引用

页码：5072 / 5074

页数：3

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