Catechol-based phosphoramidites: A new class of chiral ligands for rhodium-catalyzed asymmetric hydrogenations

被引：78

作者：

Hoen, R ^{[1
]}

van den Berg, M ^{[1
]}

Bernsmann, H ^{[1
]}

Minnaard, AJ ^{[1
]}

de Vries, JG ^{[1
]}

Feringa, BL ^{[1
]}

机构：

[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, Stratingh Inst, NL-9747 AG Groningen, Netherlands

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 09期

关键词：

D O I：

10.1021/ol049726g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and application of a new class of catechol-based phosphoramidites is described. Ees up to 99% were obtained in the rhodium-catalyzed asymmetric hydrogenation of dehydroamino acids and enamides.

引用

页码：1433 / 1436

页数：4

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