Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations

被引：204

作者：

Reddy, Ravisekhara P. ^{[1
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Univ Buffalo, Buffalo, NY 14260 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 22期

关键词：

D O I：

10.1021/ol061742l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dirhodium tetracarboxylate, Rh-2(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations.

引用

页码：5013 / 5016

页数：4

共 67 条

[1] Amidation of unfunctionalized hydrocarbons catalyzed by ruthenium cyclic amine or bipyridine complexes [J].

Au, SM ;

Huang, JS ;

Che, CM ;

Yu, WY .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (23) :7858-7864

[2] Ruthenium-mediated amidation of saturated C-H bonds and crystal structure of a bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane [J].

Au, SM ;

Zhang, SB ;

Fung, WH ;

Yu, WY ;

Che, CM ;

Cheung, KK .

CHEMICAL COMMUNICATIONS, 1998, (24) :2677-2678

[3] Catalytic hydroxylation of polypropylenes [J].

Bae, C ;

Hartwig, JF ;

Harris, NKB ;

Long, RO ;

Anderson, KS ;

Hillmyer, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (02) :767-776

[4] Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups [J].

Bae, CS ;

Hartwig, JF ;

Chung, HY ;

Harris, NK ;

Switek, KA ;

Hillmyer, MA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (39) :6410-6413

[5] CS2CO3 OR CAO AS PROMOTERS OF ETHYL N-([(4-METHYLPHENYL)SULPHONYL]OXY)CARBAMATE IN AMINATION REACTIONS [J].

BARANI, M ;

FIORAVANTI, S ;

PELLACANI, L ;

TARDELLA, PA .

TETRAHEDRON, 1994, 50 (38) :11235-11238

[6] INTRAMOLECULAR NITRENE C-H INSERTIONS MEDIATED BY TRANSITION-METAL COMPLEXES AS NITROGEN ANALOGS OF CYTOCHROME-P-450 REACTIONS [J].

BRESLOW, R ;

GELLMAN, SH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) :6728-6729

[7] Catalytic direct arylation with aryl chlorides, bromides, and iodides: Intramolecular studies leading to new intermolecular reactions [J].

Campeau, LC ;

Parisien, M ;

Jean, A ;

Fagnou, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (02) :581-590

[8] Palladium-catalyzed alkylation of aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter [J].

Chen, X ;

Li, JJ ;

Hao, XS ;

Goodhue, CE ;

Yu, JQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) :78-79

[9] Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion [J].

Davies, HML ;

Beckwith, REJ .

CHEMICAL REVIEWS, 2003, 103 (08) :2861-2903

[10] Recent advances in catalytic intramolecular C-H aminations [J].

Davies, HML ;

Long, MS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3518-3520

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