Facile functionalization of a metal carbon bond by O-atom transfer

被引：48

作者：

Conley, Brian L.

Ganesh, Somesh K.

Gonzales, Jason M.

Tenn, William J., III

Young, Kenneth J. H.

Oxgaard, Jonas

Goddard, William A., III

Periana, Roy A. ^{[1
]}

机构：

[1] Univ So Calif, Donald P & Katherine B Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

[3] CALTECH, Beckman Inst, Mat & Proc Simulat Ctr, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 28期

关键词：

D O I：

10.1021/ja062417w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors. Copyright © 2006 American Chemical Society.

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页码：9018 / 9019

页数：2

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共 16 条

[1] Deactivation of methylrhenium trioxide-peroxide catalysts by diverse and competing pathways [J].

AbuOmar, MM ;

Hansen, PJ ;

Espenson, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (21) :4966-4974

[2] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[3] Phenyl-to-oxo migration in an electrophilic rhenium(VII) dioxo complex [J].

Brown, SN ;

Mayer, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (48) :12119-12133

[4] Organometallic alkane CH activation [J].

Crabtree, RH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (24) :4083-4091

[5] TRIOXORHENIUM(VII) ALKOXIDES, DI-ISOPROPYLAMIDES, CARBOXYLATES AND RELATED-COMPOUNDS [J].

EDWARDS, P ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2695-2702

[6] Atom-transfer reactions catalyzed by methyltrioxorhenium(VII) - mechanisms and applications [J].

Espenson, JH .

CHEMICAL COMMUNICATIONS, 1999, (06) :479-488

[7] Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond [J].

Feng, Y ;

Lail, M ;

Barakat, KA ;

Cundari, TR ;

Gunnoe, TB ;

Petersen, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14174-14175

[8] Titanium complexes incorporating 1,1-bis(tert-butylamido)-1-silacycloalkane ligands:: Generation of alkyl derivatives and reactivity toward molecular oxygen [J].

Kim, SJ ;

Choi, DW ;

Lee, YJ ;

Chae, BH ;

Ko, JJ ;

Kang, SO .

ORGANOMETALLICS, 2004, 23 (03) :559-567

[9] Methyltrioxorhenium and its applications in olefin oxidation, metathesis and aldehyde olefination [J].

Kühn, FE ;

Scherbaum, A ;

Herrmann, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (24) :4149-4164

[10] Mechanistic aspects of C-H activation by Pt complexes [J].

Lersch, M ;

Tilset, M .

CHEMICAL REVIEWS, 2005, 105 (06) :2471-2526