Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

被引：27

作者：

Denmark, SE ^{[1
]}

Pan, WT ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Roger Adams Lab, Urbana, IL 61801 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 653卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

cross-coupling; alkenylsilanols; palladium catalysis;

D O I：

10.1016/S0022-328X(02)01268-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Highly substituted alkenylsilanols (1), readily prepared from commercially available simple starting materials, are efficiently-coupled with aryl or alkenyl halides in the presence of tetrabutylammonium fluoride (TBAF) and a palladium(0) catalyst. Yields are generally high and the reactions are highly stereoselective and compatible with a wide range of functional groups. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：98 / 104

页数：7

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