Selective Bifunctional Modification of a Non-catenated Metal-Organic Framework Material via "Click" Chemistry

被引：200

作者：

Gadzikwa, Tendai

Farha, Omar K.

Malliakas, Christos D.

Kanatzidis, Mercouri G.

Hupp, Joseph T. ^{[1
]}

Nguyen, SonBinh T.

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 38期

基金：

美国国家科学基金会;

关键词：

POSTSYNTHETIC MODIFICATION; COVALENT MODIFICATION; SURFACE MODIFICATION; DRUG-DELIVERY; FUNCTIONALIZATION; COORDINATION; REACTIVITY; CATALYSIS; H-2; CYCLOADDITION;

D O I：

10.1021/ja904189d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry, Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

引用

页码：13613 / +

页数：4

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