Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to nitroalkenes

被引:59
作者
Choi, H [1 ]
Hua, ZH [1 ]
Ojima, I [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
关键词
D O I
10.1021/ol0491282
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Copper-catalyzed asymmetric conjugate addition of diethylzinc to nitroalkenes using new chiral monodentate phosphoramidite ligands proceeds with high enantioselectivity up to 99% ee.
引用
收藏
页码:2689 / 2691
页数:3
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