Synthesis of Large-Area Graphene Layers on Poly-Nickel Substrate by Chemical Vapor Deposition: Wrinkle Formation

被引：858

作者：

Chae, Seung Jin ^{[2
]}

Guenes, Fethullah ^{[2
]}

Kim, Ki Kang ^{[2
]}

Kim, Eun Sung ^{[2
]}

Han, Gang Hee ^{[2
]}

Kim, Soo Min ^{[2
]}

Shin, Hyeon-Jin ^{[1
,2
]}

Yoon, Seon-Mi ^{[1
]}

Choi, Jae-Young ^{[1
]}

Park, Min Ho ^{[3
]}

Yang, Cheol Woong ^{[3
]}

Pribat, Didier ^{[4
]}

Lee, Young Hee ^{[2
]}

机构：

[1] Samsung Adv Inst Technol, Display Device & Proc Lab, Suwon 440600, South Korea

[2] Sungkyunkwan Univ, Sungkyunkwan Adv Inst Nanotechnol, Ctr Nanotubes & Nanostruct Composites, Phys Div BK21, Suwon 440746, South Korea

[3] Sungkyunkwan Univ, Dept Adv Mat Engn, Suwon 440746, South Korea

[4] Ecole Polytech, CNRS, UMR 7647, Phys Interfaces & Couches Minces Lab, F-91128 Palaiseau, France

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 22期

关键词：

CARBON NANOTUBES; SINGLE-LAYER; GRAPHITE; 6H-SIC(0001); PT(111);

D O I：

10.1002/adma.200803016

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Large-area, few-layer graphene is grown on a poly-nickel substrate using optimized CVD conditions. High temperature, short growth time, and an optimal gas mixing ratio (C2H2/H-2 = 2/45) are found to be necessary to synthesize highly crystalline few-layer grapheme, which may find applications in electronic devices. The wrinkles that are observed under all growth conditions are proposed to be formed by two processes.

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收藏

页码：2328 / +

页数：7

相关论文

共 30 条

[1]

Medium-scale carbon nanotube thin-film integrated circuits on flexible plastic substrates [J].

Cao, Qing ;

Kim, Hoon-sik ;

Pimparkar, Ninad ;

Kulkarni, Jaydeep P. ;

Wang, Congjun ;

Shim, Moonsub ;

Roy, Kaushik ;

Alam, Muhammad A. ;

Rogers, John A. .

NATURE, 2008, 454 (7203) :495-U4

[2]

Atomic structure of the 6H-SiC(0001) nanomesh [J].

Chen, W ;

Xu, H ;

Liu, L ;

Gao, XY ;

Qi, DC ;

Peng, GW ;

Tan, SC ;

Feng, YP ;

Loh, KP ;

Wee, ATS .

SURFACE SCIENCE, 2005, 596 (1-3) :176-186

[3]

Controlling the diameter, growth rate, and density of vertically aligned carbon nanotubes synthesized by microwave plasma-enhanced chemical vapor deposition [J].

Choi, YC ;

Shin, YM ;

Lee, YH ;

Lee, BS ;

Park, GS ;

Choi, WB ;

Lee, NS ;

Kim, JM .

APPLIED PHYSICS LETTERS, 2000, 76 (17) :2367-2369

[4]

Structural coherency of graphene on Ir(111) [J].

Coraux, Johann ;

N'Diaye, Alpha T. ;

Busse, Carsten ;

Michely, Thomas .

NANO LETTERS, 2008, 8 (02) :565-570

[5]

Broken symmetry and pseudogaps in ropes of carbon nanotubes [J].

Delaney, P ;

Choi, HJ ;

Ihm, J ;

Louie, SG ;

Cohen, ML .

NATURE, 1998, 391 (6666) :466-468

[6]

Intrinsic ripples in graphene [J].

Fasolino, A. ;

Los, J. H. ;

Katsnelson, M. I. .

NATURE MATERIALS, 2007, 6 (11) :858-861

[7]

Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[8]

Heteroepitaxial graphite on 6H-SiC(0001):: Interface formation through conduction-band electronic structure [J].

Forbeaux, I ;

Themlin, JM ;

Debever, JM .

PHYSICAL REVIEW B, 1998, 58 (24) :16396-16406

[9]

Spatially resolved raman spectroscopy of single- and few-layer graphene [J].

Graf, D. ;

Molitor, F. ;

Ensslin, K. ;

Stampfer, C. ;

Jungen, A. ;

Hierold, C. ;

Wirtz, L. .

NANO LETTERS, 2007, 7 (02) :238-242

[10]

Integrating single-wall carbon nanotubes into donor-acceptor nanohybrids [J].

Guldi, DM ;

Rahman, GMA ;

Jux, N ;

Tagmatarchis, N ;

Prato, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (41) :5526-5530