Nucleation in Organic Thin Film Growth: Perylene on Al2O3/Ni3Al(111)

被引：30

作者：

Casu, M. Benedetta ^{[1
,2
]}

Schoell, Achim ^{[2
]}

Bauchspiess, K. Rudolf ^{[2
]}

Huebner, Dominique ^{[2
]}

Schmidt, Thomas ^{[2
]}

Heske, Clemens ^{[2
,3
]}

Umbach, Eberhard ^{[2
,4
]}

机构：

[1] Univ Tubingen, Inst Phys & Theoret Chem, D-72076 Tubingen, Germany

[2] Univ Wurzburg, D-97074 Wurzburg, Germany

[3] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

[4] FZ Karlsruhe, D-76344 Eggenstein Leopoldshafen, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 25期

关键词：

ABSORPTION FINE-STRUCTURE; FIELD-EFFECT TRANSISTORS; MOLECULAR-ORIENTATION; AROMATIC-MOLECULES; SINGLE-CRYSTALS; SPECTROSCOPY; ADSORBATES; NEXAFS; SEMICONDUCTOR; ELECTRONICS;

D O I：

10.1021/jp809497h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular orientation of perylene thin films has been investigated using near-edge X-ray absorption fine structure spectroscopy. The presence of different molecular orientations in the monolayer, ranging from flat-lying to more upright-standing molecules, has been found and related with the different sets of growth parameters used for each sample preparation. The same molecular tuning has been observed in the multilayer regime. It is shown that it is possible to explain these results by using concepts of the atomistic theory of nucleation. Regarding perylene on Al2O3/Ni3Al(111) as a model system for organic layers in, for example, organic field effect transistors, our findings raise some questions about the suitability of perylene as an active layer in a real device.

引用

页码：10990 / 10996

页数：7

共 44 条

[1] Evolution of dislocations in perylene films with thickness and deposition rate [J].

Beigmohamadi, M. ;

Niyamakom, P. ;

Farahzadi, A. ;

Kremers, S. ;

Michely, T. ;

Wuttig, M. .

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2008, 2 (01) :1-3

[2] A completely flexible organic transistor obtained by a one-mask photolithographic process [J].

Bonfiglio, A ;

Mameli, F ;

Sanna, O .

APPLIED PHYSICS LETTERS, 2003, 82 (20) :3550-3552

[3] CRYSTAL + MOLECULAR STRUCTURE OF PERYLENE [J].

CAMERMAN, A ;

TROTTER, J .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1964, 279 (1376) :129-+

[4] Photoemission electron microscopy of diindenoperylene thin films [J].

Casu, M. B. ;

Biswas, I. ;

Nagel, M. ;

Nagel, P. ;

Schuppler, S. ;

Chasse, T. .

PHYSICAL REVIEW B, 2008, 78 (07)

[5] Epitaxial growth of a crystalline organic semiconductor: Perylene/Cu{110} [J].

Chen, Q ;

Rada, T ;

McDowall, A ;

Richardson, NV .

CHEMISTRY OF MATERIALS, 2002, 14 (02) :743-749

[6] Field-effect transistors on tetracene single crystals [J].

de Boer, RWI ;

Klapwijk, TM ;

Morpurgo, AF .

APPLIED PHYSICS LETTERS, 2003, 83 (21) :4345-4347

[7]

Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO

[8]

2-9

[9] Low-cost all-polymer integrated circuits [J].

Drury, CJ ;

Mutsaers, CMJ ;

Hart, CM ;

Matters, M ;

de Leeuw, DM .

APPLIED PHYSICS LETTERS, 1998, 73 (01) :108-110

[10] Structure, bonding, and growth at a metal-organic interface in the weak chemisorption regime: Perylene-Ag(111) [J].

Eremtchenko, M ;

Bauer, D ;

Schaefer, JA ;

Tautz, FS .

JOURNAL OF MATERIALS RESEARCH, 2004, 19 (07) :2028-2039

← 1 2 3 4 5 →