Gold and silver complexes with the ferrocenyl phosphine FcCH2PPh2 [Fe = (η5-C5H5)Fe(η5-C5H4)]

被引：35

作者：

Barranco, EN

Crespo, O

Gimeno, MC

Laguna, A ^{[1
]}

Jones, PG

Ahrens, B

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Dept Quim Inorgan, CSIC, E-50009 Zaragoza, Spain

[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 04期

关键词：

D O I：

10.1021/ic9905446

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Linear gold(I) and silver(I) complexes with the ferrocenyl phosphine FcCH(2)PPh(2) [Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] of the types [AuR(PPh(2)CH(2)Fc)], [M(PPh3)(PPh(2)CH(2)Fc)]OTf, and [M(PPh(2)CH(2)Fc)(2)]OTf (M = Au, Ag) have been obtained. Three-coordinate gold(I) and silver(I) derivatives of the types [AuCl(PPh(2)CH(2)Fc)(2)] and [M(PPh(2)CH(2)Fc)(3)]X (M = Au, X = ClO4; M = Ag, X = OTf) have been obtained from the corresponding gold and silver precursors in the appropriate molar ratio, although some of them are involved in equilibria in solution. The crystal structures of [AuR(PPh(2)CH(2)Fc)] (R = Cl, C6F5), [AuL(PPh(2)CH(2)Fc)]OTf (L = PPh3, FcCH(2)PPh(2)). [Au(C6F5)(3)(PPh(2)CH(2)Fc)], and [Ag(PPh(2)CH(2)Fc)(3)]OTf have been determined by X-ray diffraction studies.

引用

收藏

页码：680 / 687

页数：8

相关论文

共 43 条

[21] Synthesis and reactivity of the ferrocene-derived phosphine [Fe(eta-C5H5)-{eta-C5H4CH2P(CH2OH)(2)}] [J].

Goodwin, NJ ;

Henderson, W ;

Nicholson, BK ;

Sarfo, JK ;

Fawcett, J ;

Russell, DR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4377-4384

[22] FcCH(2)P(CH2OH)(2): A new, reactive yet air-stable ferrocene-derived phosphine [Fc=(eta-C5H5)FeC5H4] [J].

Goodwin, NJ ;

Henderson, W ;

Sarfo, JK .

CHEMICAL COMMUNICATIONS, 1996, (13) :1551-1552

[23] Coordination complexes of the hydroxymethylphosphine FcCH2P(CH2OH), [Fc = (η5-C5H5)Fe(η5-C5H4)] and the x-ray crystal structure of the cationic gold bis(phosphine) complex [Au{FcCH2P(CH2OH)2}2]Cl [J].

Goodwin, NJ ;

Henderson, W .

POLYHEDRON, 1998, 17 (23-24) :4071-4077

[24] An air-stable, primary alkylphosphine: FcCH(2)PH(2) [Fc=(eta(5)-C5H5)Fe(eta(5)-C5H4)] [J].

Goodwin, NJ ;

Henderson, W ;

Nicholson, BK .

CHEMICAL COMMUNICATIONS, 1997, (01) :31-32

[25]

GUY JJ, 1976, ACTA CRYSTALLOGR B, V32, P1937, DOI 10.1107/S056774087601251X

[26]

HAYASHI T, 1995, HOMOGENEOUS CATALYSI, pCH2

[27] [MU-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]BIS(CHLOROGOLD) - SYNTHESIS, FE-57 AND AU-197 MOSSBAUER-SPECTROSCOPY, X-RAY CRYSTAL-STRUCTURE, AND ANTITUMOR-ACTIVITY [J].

HILL, DT ;

GIRARD, GR ;

MCCABE, FL ;

JOHNSON, RK ;

STUPIK, PD ;

ZHANG, JH ;

REIFF, WM ;

EGGLESTON, DS .

INORGANIC CHEMISTRY, 1989, 28 (18) :3529-3533

[28] CHLORO[DIFERROCENYL(PHENYL)PHOSPHINE]GOLD(I) [J].

JONES, PG ;

ERDBRUGGER, CF ;

HOHBEIN, R ;

SCHWARZMANN, E .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :1302-1303

[29] ORGANOMETALLIC DERIVATIVES .6. SYNTHESIS AND REACTIVITY OF SOME (FERROCENYLMETHYL)PHOSPHINES [J].

MARR, G ;

WHITE, TM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (18) :1955-1958

[30] STRUCTURES OF 2 GOLD(I) COMPLEXES WITH TRICYCLOHEXYLPHOSPHINE - [(CY3P)AUCL] AND [(CY3P)2AU]+.CL- [J].

MUIR, JA ;

MUIR, MM ;

PULGAR, LB ;

JONES, PG ;

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (AUG) :1174-1176

← 1 2 3 4 5 →