New heteroaromatic π-ligands containing boron

被引：1

作者：

Ashe, AJ ^{[1
]}

Bajko, Z ^{[1
]}

Fang, XD ^{[1
]}

Kampf, JW ^{[1
]}

Yang, H ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 4-5期

关键词：

D O I：

10.1080/10426500490426610

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heteroaromatic anions 2-(diisopropylamino)-1,2-thiaborolide(2a), 1-ethyl-2-phenyl-1,2-azaborolide(2b), and 2-(diisopropylamino)-1,2-oxaborolide(2c) have been prepared by a multi-step synthesis using the Grubbs ring-closing metathesis. Reactions of 2a, 2b, and 2c with Cp*ZrCl3 afforded the corresponding Zr(IV) complexes 3.

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页码：711 / 714

页数：4

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