1,4-phosphaboratabenzene:: A heteroaromatic π-ligand containing boron and phosphorus

被引：12

作者：

Ashe, AJ ^{[1
]}

Bajko, Z ^{[1
]}

Carr, MD ^{[1
]}

Kampf, JW ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 05期

关键词：

D O I：

10.1021/om0209733

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,4-dihydro-4-(diisopropylamino)-2,6-dimethyl-1-phenyl-1,4-phosphaborin (6) with Mn-2(CO)(10) affords 7, the Mn(CO)(3) complex of 4-(diisopropylamino)-2,6-dimethyl-1,4-phosphaboratabenzene. Reaction of 6 with Li followed by (Cp*RuCl](4) gives the ruthenium(II) complex 8. Crystal structures of 6-8 have been determined.

引用

收藏

页码：910 / 912

页数：3

相关论文

共 36 条

[1] CONFORMATIONAL PREFERENCES AND ROTATIONAL BARRIERS IN POLYENE-ML3 TRANSITION-METAL COMPLEXES [J].

ALBRIGHT, TA ;

HOFMANN, P ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (23) :7546-7557

[2] CONFORMATIONAL PREFERENCES OF SUBSTITUTED CYCLOPENTADIENYL AND HETEROCYCLOPENTADIENYL COMPLEXES [J].

ALBRIGHT, TA ;

HOFFMANN, R .

CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (04) :1578-1590

[3] ROTATIONAL BARRIERS AND CONFORMATIONS IN TRANSITION-METAL COMPLEXES [J].

ALBRIGHT, TA .

ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (05) :149-155

[4] Synthesis and coordination chemistry of 3a,7a-azaborindenyl, a new isoelectronic analogue of the indenyl ligand [J].

Ashe, AJ ;

Yang, H ;

Fang, XD ;

Kampf, JW .

ORGANOMETALLICS, 2002, 21 (22) :4578-4580

[5] A synthesis of aromatic five- and six-membered B-N heterocycles via ring closing metathesis [J].

Ashe, AJ ;

Fang, XD .

ORGANIC LETTERS, 2000, 2 (14) :2089-2091

[6] Aminoboratabenzenes. An evaluation of the exocyclic B-N interaction [J].

Ashe, AJ ;

Kampf, JW ;

Muller, C ;

Schneider, M .

ORGANOMETALLICS, 1996, 15 (01) :387-393

[7] 1,2-benzothiaborolide: A new heteroaromatic analogue of indenyl [J].

Ashe, AJ ;

Kampf, JW ;

Schiesher, M .

ORGANOMETALLICS, 2000, 19 (23) :4681-4683

[8] 1,3-benzothiaborolide: A new heteroaromatic anion [J].

Ashe, AJ ;

Fang, XG ;

Kampf, JW .

ORGANOMETALLICS, 1998, 17 (12) :2379-2381

[9] 1,3-thiaborolide: A new heteroaromatic surrogate for cyclopentadienide [J].

Ashe, AJ ;

Fang, XG ;

Kampf, JW .

ORGANOMETALLICS, 1999, 18 (10) :1821-1823

[10] 1,2-thiaborolide:: A new heteroaromatic π-ligand containing boron and sulfur [J].

Ashe, AJ ;

Fang, XD ;

Kampf, JW .

ORGANOMETALLICS, 2000, 19 (24) :4935-4937

← 1 2 3 4 →