Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes

被引：29

作者：

Jeganmohan, M ^{[1
]}

Shanmugasundaram, M ^{[1
]}

Chang, KJ ^{[1
]}

Cheng, CH ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b206488j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition reaction of silylstannanes with allenes in the presence of Pd-2(dba)(3).dba in toluene affords (E)-alkenylsilanes having an allylstannane moiety exclusively in good to excellent yields.

引用

页码：2552 / 2553

页数：2

共 17 条

[1]

ABEL EW, 1995, COMPREHENSIVE ORGA 2, V11

[2] Highly regioselective and stereoselective allylation of aldehydes via palladium-catalyzed in situ hydrostannylation of allenes [J].

Chang, HM ;

Cheng, CH .

ORGANIC LETTERS, 2000, 2 (22) :3439-3442

[3] Palladium-catalyzed synthesis of 1,3-dienes from allenes and organic halides [J].

Chang, HM ;

Cheng, CH .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (06) :1767-1773

[4] Palladium-catalyzed three-component assembling of allenes, organic halides, and arylboronic acids [J].

Huang, TH ;

Chang, HM ;

Wu, MY ;

Cheng, CH .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (01) :99-105

[5]

Kang SK, 2002, ANGEW CHEM INT EDIT, V41, P343, DOI 10.1002/1521-3773(20020118)41:2<343::AID-ANIE343>3.0.CO

[6]

2-1

[7] PALLADIUM-CATALYZED ADDITION OF THE SILICON TIN BOND TO ALK-1-YNES AND 1,1-DIMETHYLALLENE [J].

MITCHELL, TN ;

KILLING, H ;

DICKE, R ;

WICKENKAMP, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (06) :354-355

[8] UNEXPECTED REVERSAL OF REGIOSELECTIVITY IN THE PALLADIUM-CATALYZED ADDITION OF THE TIN GERMANIUM BOND TO ALLENES [J].

MITCHELL, TN ;

SCHNEIDER, U ;

FROHLING, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (03) :C53-C56

[9] PALLADIUM-CATALYZED ADDITION OF TIN-TIN AND TIN-SILICON BONDS TO ALLENES [J].

MITCHELL, TN ;

SCHNEIDER, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 407 (03) :319-327

[10] Palladium-catalysed borylsilylation and borylstannylative dimerization of 1,2-dienes [J].

Onozawa, S ;

Hatanaka, Y ;

Tanaka, M .

CHEMICAL COMMUNICATIONS, 1999, (18) :1863-1864

← 1 2 →