Metal-Organic Frameworks (MOFs) as Heterogeneous Catalysts for the Chemoselective Reduction of Carbon-Carbon Multiple Bonds with Hydrazine

被引：85

作者：

Dhakshinamoorthy, Amarajothi ^{[1
,2
]}

Alvaro, Mercedes ^{[1
,2
]}

Garcia, Hermenegildo ^{[1
,2
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain

[2] Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 14-15期

关键词：

alkynes; hydrazines; metal-organic frameworks; olefins; reduction; HYDROGEN STORAGE; THERMAL-STABILITY; PALLADIUM; ALUMINUM;

D O I：

10.1002/adsc.200900362

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The as-synthesized metal-organic frameworks (MOFs), particularly that based on aluminium coordinated with benzenedicarboxylic acid, constitute selective catalysts for the reduction of carbon-carbon multiple bonds in alkenes, alkynes and alpha,beta-unsaturated esters with hydrazine hydrate in acetonitrile under mild conditions. The present protocol enjoys advantages such as convenient reaction conditions and benign, reusable and cost effective catalyst.

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页码：2271 / 2276

页数：6

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