Assessing the effect of the matrix in resonant infrared MAPLE

被引：21

作者：

Bubb, D. M.

Sezer, A. O.

Gripenburg, J.

Collins, B.

Brookes, E.

机构：

[1] Rutgers State Univ, Dept Phys, Camden, NJ 08102 USA

[2] Naval Res Lab, Washington, DC 20375 USA

[3] Univ Penn, Dept Chem, Philadelphia, PA USA

来源：

APPLIED SURFACE SCIENCE | 2007年 / 253卷 / 15期

基金：

美国国家科学基金会;

关键词：

MAPLE; laser processing; polymers;

D O I：

10.1016/j.apsusc.2007.01.109

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ablation yield of polyethylene glycol is measured as a function of laser pulse energy and polymer molecular weight for both free running and Q-switched Er:YAG lasers. The results show that the deposition rate is dependent on the absorption coefficient in a way that is consistent with the blow-off ablation model but that the linear dependence of the efficiency on laser pulse energy is also consistent with a steady-state ablation model. The results for both lasers are remarkably similar given that the pulse durations are 350 mu s and 85 ns, respectively. Furthermore, polystyrene thin films are deposited as well and it is found that the morphology depends on the THF/MeOH ratios in the matrices. The significance of these results is discussed as well as future directions for this research. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：6465 / 6470

页数：6

共 35 条

[1] THERMODYNAMIC PROPERTIES OF ORGANIC OXYGEN COMPOUNDS .11. THERMODYNAMIC PROPERTIES FROM 10 TO 330 DEGREES K OF ISOPROPYL ALCOHOL [J].