Nitrobenzene reduction catalyzed by carbon: does the reaction really belong to carbocatalysis?

被引：43

作者：

Wu, Shuchang ^{[1
]}

Wen, Guodong ^{[1
]}

Wang, Jia ^{[1
]}

Rong, Junfeng ^{[2
]}

Zong, Baoning ^{[2
]}

Schloegl, Robert ^{[3
]}

Su, Dang Sheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

[2] Res Inst Petr Proc, Beijing 100083, Peoples R China

[3] Max Planck Gesell, Fritz Harber Inst, Dept Inorgan Chem, D-14195 Berlin, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 12期

关键词：

OXIDATIVE DEHYDROGENATION; HYDRAZINE HYDRATE; AEROBIC OXIDATION; GRAPHENE OXIDE; GRAPHITE OXIDE; N-BUTANE; NANOTUBES; HYDROGENATION; NITROARENES; EFFICIENT;

D O I：

10.1039/c4cy00811a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reduction of nitrobenzene could proceed in the presence of carbon. The activity mainly originated from carbonyl groups on the carbon surface instead of metal impurities which were embedded in the carbon.

引用

页码：4183 / 4187

页数：5

共 32 条

[1] Carbon nanotubes contain metal impurities which are responsible for the "electrocatalysis" seen at some nanotube-modified electrodes [J].

Banks, CE ;

Crossley, A ;

Salter, C ;

Wilkins, SJ ;

Compton, RG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (16) :2533-2537

[2] On the Role of Metal Contaminants in Catalyses with FeCl3 [J].

Buchwald, Stephen L. ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (31) :5586-5587

[3] The influence of the residual growth catalyst in functionalized carbon nanotubes on supported Pt nanoparticles applied in selective olefin hydrogenation [J].

Chen, Peirong ;

Chew, Ly May ;

Xia, Wei .

JOURNAL OF CATALYSIS, 2013, 307 :84-93

[4] Graphite oxide: a selective and highly efficient oxidant of thiols and sulfides [J].

Dreyer, Daniel R. ;

Jia, Hong-Peng ;

Todd, Alexander D. ;

Geng, Jianxin ;

Bielawski, Christopher W. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (21) :7292-7295

[5] Graphene Oxide: A Convenient Carbocatalyst for Facilitating Oxidation and Hydration Reactions [J].

Dreyer, Daniel R. ;

Jia, Hong-Peng ;

Bielawski, Christopher W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6813-6816

[6] Reduced graphene oxide as a catalyst for hydrogenation of nitrobenzene at room temperature [J].

Gao, Yongjun ;

Ma, Ding ;

Wang, Chunlei ;

Guan, Jing ;

Bao, Xinhe .

CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2432-2434

[7]

HAN BH, 1985, TETRAHEDRON LETT, V26, P6233

[8] Graphite oxide as an efficient and durable metal-free catalyst for aerobic oxidative coupling of amines to imines [J].

Huang, Hai ;

Huang, Jun ;

Liu, Yong-Mei ;

He, He-Yong ;

Cao, Yong ;

Fan, Kang-Nian .

GREEN CHEMISTRY, 2012, 14 (04) :930-934

[9] Nanoscale Fe2O3-Based Catalysts for Selective Hydrogenation of Nitroarenes to Anilines [J].

Jagadeesh, Rajenahally V. ;

Surkus, Annette-Enrica ;

Junge, Henrik ;

Pohl, Marga-Martina ;

Radnik, Joerg ;

Rabeah, Jabor ;

Huan, Heming ;

Schuenemann, Volker ;

Brueckner, Angelika ;

Beller, Matthias .

SCIENCE, 2013, 342 (6162) :1073-1076

[10] Efficient and highly selective iron-catalyzed reduction of nitroarenes [J].

Jagadeesh, Rajenahally V. ;

Wienhoefer, Gerrit ;

Westerhaus, Felix A. ;

Surkus, Annette-Enrica ;

Pohl, Marga-Martina ;

Junge, Henrik ;

Junge, Kathrin ;

Beller, Matthias .

CHEMICAL COMMUNICATIONS, 2011, 47 (39) :10972-10974

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